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REDOX WS1
Identify the species being oxidized and reduced in each of the following reactions
a. Cr+1 + Sn+4 Cr+3 + Sn+2
b. 3Hg+2 + 2Fe 3Hg + 2Fe+3
c. 2As + 3Cl2 AsCl3
d. NaBr + Cl2 NaCl + Br2
e. Fe2O3 + 3CO 2Fe + 3CO2

Respuesta :

a.
Cr⁺¹ + Sn⁺⁓ ⇒ Cr⁺³ + Sn⁺²
Cr⁺¹ ⇒ Cr⁺³ + 2e⁻
The half-reaction of oxidation: chrome is anĀ electron donor,Ā losses 2 electrons ie it is oxidized
2e⁻ + Sn⁺⁓ ⇒ Sn⁺²
The half-reaction of reduction: tin is anĀ electron acceptor, receives 2 electrons, ieĀ it is reduced

b.
3Hg⁺² + 2Fe ⇒ 3Hg + 2Fe⁺³
2Fe ⇒  2Fe⁺³ + 6e⁻ 
The half-reaction of oxidation: iron is anĀ electron donor,Ā losses 3 electrons ie it is oxidized
6e⁻ + 3Hg⁺² + ⇒ 3HgĀ 
The half-reaction of reduction: mercury is anĀ electron acceptor, receives 2 electrons, ieĀ it is reduced

c.
2As + 3Cl
₂ ⇒ 2AsClā‚ƒ
2As ⇒ 2As⁺³ + 6e⁻ 
The half-reaction of oxidation: arsenic is anĀ electron donor,Ā losses 3 electrons ie it is oxidized
6e⁻ + 3Cl₂ ⇒ 6Cl⁻
The half-reaction of reduction: chlorine is anĀ electron acceptor, receives 1 electron, ieĀ it is reduced

d.
NaBr + Cl
₂ ⇒ NaCl + Brā‚‚Ā 
2Br⁻ ⇒  Brā‚‚ + 2e⁻ 
The half-reaction of oxidation: bromine is anĀ electron donor,Ā losses 1 electron ie it is oxidized
2e⁻ + Cl₂ ⇒ 2Cl⁻
The half-reaction of reduction: chlorine is anĀ electron acceptor, receives 1 electron, ieĀ it is reduced

e.
Feā‚‚Oā‚ƒĀ + 3CO ⇒ 2Fe + 3COā‚‚
3C⁺² ⇒ 3C⁺⁓ + 6e⁻
The half-reaction of oxidation: carbon is anĀ electron donor,Ā losses 2 electrons ie it is oxidized
6e⁻ +Ā  2Fe⁺³ ⇒ 2FeĀ 
The half-reaction of reduction: iron is anĀ electron acceptor, receives 3 electrons, ieĀ it is reduced